|
|
Octadec-9-ene-1,18-dioic-acid + CoA + ATP <=> (9Z)-17-carboxyheptadec-9-enoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
|
MetaCyc:
RXN-16418
|
|
|
|
oleic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> omega-hydroxy_oleic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
|
MetaCyc:
RXN-16400
|
|
|
|
ferulic_acid + ATP + CoA <=> feruloyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
6.2.1.34
trans-feruloyl-CoA synthase
|
–
–
|
|
BRENDA:
BS27
KEGG:
R02194
MetaCyc:
6.2.1.34-RXN
SABIO-RK:
2167
|
|
|
|
omega-hydroxy_oleic_acid + NADP+ <=> 18-Oxooleate + NADPH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-16416
|
|
|
|
L-phenylalanine <=> Cinnamic_acid + NH3
|
4.3.1.1
aspartate ammonia-lyase
4.3.1.23
tyrosine ammonia-lyase
4.3.1.24
phenylalanine ammonia-lyase
4.3.1.25
phenylalanine/tyrosine ammonia-lyase
4.3.1.31
L-tryptophan ammonia lyase
4.3.1.5
phenylalanine ammonia-lyase
|
–
–
–
–
–
–
|
|
BRENDA:
BR3427;
BS445625
KEGG:
R00697
MetaCyc:
PHENYLALANINE-AMMONIA-LYASE-RXN
SABIO-RK:
1076
|
|
|
|
16-hydroxypalmitic_acid + CoA + ATP <=> 16-hydroxypalmitoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
|
BRENDA:
BS379209
MetaCyc:
RXN-16389
SABIO-RK:
13099
|
|
|
|
S-adenosyl-L-methionine + caffeic_acid <=> H+ + ferulic_acid + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
2.1.1.68
caffeate O-methyltransferase
|
–
–
|
|
BRENDA:
BR43911
KEGG:
R03366
MetaCyc:
RXN-1104
SABIO-RK:
14976
|
|
|
|
22-carboxy-docosanoyl-CoA + sn-glycerol_3-phosphate <=> CoA + 2-C22:0-DCA-LPA
|
2.3.1.198
glycerol-3-phosphate 2-O-acyltransferase
|
–
|
|
MetaCyc:
RXN-13734
|
|
|
|
22-oxo-docosanoyl-CoA + NADP+ + H2O <=> 22-carboxy-docosanoyl-CoA + NADPH + H+
|
1.2.1
|
–
|
|
MetaCyc:
RXN-12157
|
|
|
|
18-Oxooleate + NADP+ + H2O <=> Octadec-9-ene-1,18-dioic-acid + NADPH + H+
|
1.2.1
|
–
|
|
MetaCyc:
RXN-16417
|
|
|
|
Cinnamic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> p-coumaric_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
|
MetaCyc:
TRANS-CINNAMATE-4-MONOOXYGENASE-RXN
|
|
|
|
22-hydroxy-docosanoyl-CoA + NADP+ <=> 22-oxo-docosanoyl-CoA + NADPH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-12156
|
|
|
|
oleoyl-CoA + H2O <=> H+ + oleic_acid + CoA
|
2.3.1.9
acetyl-CoA C-acetyltransferase
3.1.1.1
carboxylesterase
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
|
–
–
–
–
–
–
|
|
BRENDA:
BS115467
KEGG:
R08176
MetaCyc:
RXN-9666
SABIO-RK:
6580
|
|
|
|
palmitoyl-CoA + H2O <=> H+ + palmitate + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
3.1.1.1
carboxylesterase
3.1.1.23
acylglycerol lipase
3.1.1.5
lysophospholipase
3.1.2
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
–
–
–
–
–
–
–
–
–
|
|
BRENDA:
BR48147;
BS115468
KEGG:
R01274;
R08174;
R09450
MetaCyc:
PALMITOYL-COA-HYDROLASE-RXN;
RXN-16395;
RXN-9624
SABIO-RK:
1490;
6573
|
|
|
|
p-coumaric_acid + reduced_[NADPH-hemoprotein_reductase] + O2 <=> caffeic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
|
MetaCyc:
RXN-1103
|
|
|
|
S-adenosyl-L-methionine + caffeoyl-CoA <=> H+ + feruloyl-CoA + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
|
–
|
|
BRENDA:
BR43863
KEGG:
R01942
MetaCyc:
CAFFEOYL-COA-O-METHYLTRANSFERASE-RXN
|
|
|
|
palmitate + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 16-hydroxypalmitic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
|
MetaCyc:
RXN-16398
|
|
|
|
feruloyl-CoA + tyramine <=> H+ + feruloyltyramine + CoA
|
2.3.1.110
tyramine N-feruloyltransferase
|
–
|
|
BRENDA:
BR43975
KEGG:
R02385
MetaCyc:
TYRAMINE-N-FERULOYLTRANSFERASE-RXN
|
|
|
|
caffeic_acid + CoA + ATP <=> caffeoyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
|
–
|
|
BRENDA:
BS26
KEGG:
R01943
MetaCyc:
RXN-1126
SABIO-RK:
12842;
1996
|
|
|
|
behenoyl-CoA + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 22-hydroxy-docosanoyl-CoA + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
|
MetaCyc:
RXN-12155
|
|